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  • 什么是氯化聚乙烯?
  • 本站编辑:杭州宇先化工有限公司发布日期:2018-08-30 22:12 浏览次数:

氯化聚乙烯(CPE)

氯化聚乙烯(CPE)为饱和高分子材料,外观为白色粉末,无毒无味,具有优良的耐侯性、耐臭氧、耐化学药品及耐老化性能,具有良好的耐油性、阻燃性及着色性能。韧性良好(在-30℃仍有柔韧性),与其它高分子材料具有良好的相容性,分解温度较高,分解产生HCL,HCL能催化CPE的脱氯反应.

Chlorinated polyethylene (CPE) is a kind of saturated polymer material with white appearance, non-toxic and tasteless, excellent weather resistance, ozone resistance, chemical resistance and aging resistance, good oil resistance, flame retardancy and coloring performance. Good toughness (still flexible at - 30 C), good compatibility with other polymer materials, high decomposition temperature, decomposition to produce HCL, HCL can catalyze the dechlorination of CPE.

氯化聚乙烯的水相法用的比较多,这种生产成本低,污染性差。还有一种是悬浮法,它比较成熟,国产的可以进行二次开发以及应用得到很快的发展,干燥的速度快。在储罐、钢结构中用的比较多,以提高施工的安全性。

The aqueous phase method of chlorinated polyethylene is used more, and this production cost is low and the pollution is poor. There is also a suspension method, it is more mature, domestic secondary development and application can be quickly developed, drying speed is fast. In storage tanks, steel structures are used more in order to improve the safety of construction.

国内氯化聚乙烯(CPE)型号一般用如135A、140B、239C等来标识,其中靠前位数字1和2表示残余结晶度(TAC值)的大小,1代表TAC值在0-10%,2表示TAC值>10%,第2、3位数字表示氯含量,如35表示氯含量为35%,最后一位是字母ABC,用来表示原料PE分子量的大小,A为最大,C为比较小。

Domestic CPE models are generally marked with 135A, 140B, 239C, etc. The first digits 1 and 2 represent the size of residual crystallinity (TAC value), 1 represents the TAC value of 0-10%, 2 represents the TAC value > 10%, the second and third digits represent the chlorine content, such as 35 represents the chlorine content of 35%, the last digit is the letter ABC, used to indicate the value of TAC. The molecular weight of raw material PE is A, C is the smallest.

分子量的影响:氯化聚乙烯(CPE)的A型料分子量较大,熔融黏度也大,其黏度与PVC较匹配,在PVC中分散效果较好,可以形成理想的网络状的分散形态,所以一般选择CPE的A型料做PVC的改性剂。

The influence of molecular weight: The molecular weight and melting viscosity of CPE are higher, and the viscosity of CPE is better matched with PVC. The dispersion effect of CPE in PVC is better, and it can form an ideal network-like dispersion form. Therefore, CPE is generally chosen as the modifier of PVC.

主要应用于:电线电缆(煤矿用电缆、UL及VDE等标准中规定的电线),液压胶管,车用胶管,胶带,胶板,PVC型材管材改性,磁性材料,ABS改性等等。特别是电线电缆行业、汽车配件制造业的发展,带动了对橡胶型CPE的消费需求。橡胶型CPE是一种综合性能优良、耐热氧臭氧老化、阻燃性佳的特种合成橡胶。

Mainly used in: wire and cable (coal mine cables, UL and VDE standards stipulated in the wire), hydraulic hose, automotive hose, tape, rubber board, PVC profile pipe material modification, magnetic materials, ABS modification and so on. Especially the development of wire and cable industry and auto parts manufacturing industry has led to the demand for rubber CPE. Rubber CPE is a kind of special synthetic rubber with excellent comprehensive properties, heat-resistant, oxygen-ozone aging and good flame retardancy.